The following example demonstrates how to create a style to change the layout of the printed pages by providing a new ControlTemplate that will place the page headers and footers at the top of each page and display an orange border around the area where the grid is printed.

The Print method will be called in the button's Click event, whose implementation is provided below.

XAML
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<Grid xmlns:xcdg="http://schemas.xceed.com/wpf/xaml/datagrid"
      xmlns:local="clr-namespace:Xceed.Wpf.Documentation">
  <Grid.Resources>
    <xcdg:DataGridCollectionViewSource x:Key="cvs_employees"
                                     Source="{Binding Source={x:Static Application.Current},
                                                        Path=Employees}"/>
    <Style x:Key="page_style" TargetType="{x:Type xcdg:DataGridPageControl}">
      <Setter Property="Template">
        <Setter.Value>
          <ControlTemplate TargetType="{x:Type xcdg:DataGridPageControl}">
            <DockPanel>
              <StackPanel xcdg:DataGridPageControl.IsPageHeadersHost="True"
                          DockPanel.Dock="Top"/>
              <StackPanel xcdg:DataGridPageControl.IsPageFootersHost="True"
                          DockPanel.Dock="Top"/>
              <Border BorderThickness="2"
                      BorderBrush="Orange"
                      xcdg:DataGridPageControl.IsDataGridHost="True"
                      DockPanel.Dock="Bottom"/>
            </DockPanel>
          </ControlTemplate>
        </Setter.Value>
      </Setter>
    </Style>
  </Grid.Resources>
  <DockPanel>
    <Button Content="Print Grid"
            Click="PrintGrid"
            DockPanel.Dock="Top"/>
    <xcdg:DataGridControl x:Name="EmployeesGrid"
                          ItemsSource="{Binding Source={StaticResource cvs_employees}}">
      <xcdg:DataGridControl.PrintView>
       <xcdg:PrintTableView PageStyle="{StaticResource page_style}">
          <xcdg:PrintTableView.PageHeaders>
            <DataTemplate>
              <TextBlock Text="Xceed WPF Documentation"
                         HorizontalAlignment="Center"
                         FontWeight="Bold"
                         FontSize="20"/>
            </DataTemplate>
            <DataTemplate>
              <TextBlock Text="Printing Example"
                         HorizontalAlignment="Center"
                         FontSize="16"/>
            </DataTemplate>
          </xcdg:PrintTableView.PageHeaders>
          <xcdg:PrintTableView.PageFooters>
            <DataTemplate>
              <StackPanel HorizontalAlignment="Right"
                          Orientation="Horizontal">
                <TextBlock Text="Page "/>
                <TextBlock Text="{xcdg:ViewBinding CurrentPageNumber}"/>
              </StackPanel>  
            </DataTemplate>
          </xcdg:PrintTableView.PageFooters>
        </xcdg:PrintTableView>
      </xcdg:DataGridControl.PrintView>
    </xcdg:DataGridControl>
  </DockPanel>
</Grid>
VB.NET
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Private Sub PrintGrid( ByVal sender As Object, ByVal e As RoutedEventArgs )
  Me.EmployeeGrid.Print( "Employee_Grid", True )
End Sub
C#
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private void PrintGrid( object sender, RoutedEventArgs e )
{
 this.EmployeesGrid.Print( "Employee_Grid", true );
}